ammonium hydroxide hazards

fExposure can irritate the eyes, nose and throat. 0000003612 00000 n When employees work with industrial chemicals, they often are not using products they will find at home. {�k��Ο�(���(�?�s_���/C�V��0�ਇm�l8a���;�����•|�1�3m����3~N�֙���y����4�?�4�[��JEL�. Tel: (201) 796-7100. Avoid ammonium hydroxide contact with chemicals such as mercury, chlorine, iodine, bromine, silver oxide or hypochlorites; they can form explosive compounds. 0000003577 00000 n <> Tetramethylammonium hydroxide (TMAH or TMAOH) is a quaternary ammonium salt with the molecular formula N(CH 3) 4 + OH −.It is commonly encountered as concentrated solutions in water or methanol.The solid and solutions are colorless, or yellowish if impure. AMMONIUM HYDROXIDE can be found in 65 products. Ammonium hydroxide itself is non-combustible. Ammonia reacts with strong oxidizers, acids, halogens (including chlorine bleach), and salts of silver, zinc, copper, and other heavy metals. 0000001700 00000 n %%EOF decomposition products. Skin Corrosion/irritation Category 1 B. 0000000016 00000 n Tetramethylammonium hydroxide is a solid in the hydrated form or a colorless liquid with a strong ammonia -like odor. trailer Although the name ammonium hydroxide suggests an alkali with composition [NH 4 +][OH −], it is actually impossible to isolate samples of NH 4 OH. 61 0 obj <>stream 0000000976 00000 n 0000005636 00000 n Health issue . Molecular Weight 35.05 . 0000018450 00000 n Ammonia: LC50, Water Flea (Daphnia magna): 0.66 mg/L 48 h Persistence and Degradability: Expected to be readily biodegradable. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 0000004083 00000 n Fair Lawn, NJ 07410. P271 - Use only outdoors or in a well-ventilated area. Safety Data Sheet (SDS) SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Ammonium Hydroxide 1.1 M - 14.8 M Flinn Scientific, Inc. P.O. Ammonium hydroxide is a colorless liquid with a strong odor and bad taste. stream endobj Concentrated solution violent to explosive reaction with many compounds e.g. 0000004611 00000 n 0000019272 00000 n Ammonium hydroxide solution ACS reagent Synonym: Ammonia aqueous, Ammonia water CAS Number 1336-21-6. Used in everything from household cleaners to industrial processes, it is toxic in all solutions. 28 0 obj <> endobj Compliant with the OSHA Hazard Communication Standard 1910.1200 and aligned with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Made in the United States of America 0000001520 00000 n Other Hazards Ammonium hydroxide is very volatile and may release ammonia as a gas. Ammonium hydroxide is a caustic inorganic base (an alkaline substance). Ammonia (H3N) is a gas. Compare Products: Select up to 4 products. The following acute (short-term) health effects may occur immediately or shortly after exposure to Ammonium Hydroxide: fContact can severely irritate and burn the skin and eyes leading to eye damage. P270 - Do not eat, drink or smoke when using this product. 0 colorless liquid with a strong odor and bad taste, Four Steps to Conducting a Job Safety Analysis in the Canadian Workplace, Train over any hazardous chemicals that employees may be exposed to, Train employees to detect and respond … The major hazards encountered in the use and handling of ammonium hydroxide stem from its toxicologic properties. Unknown Acute Toxicity (GHS-US) No data available. §ðÔ¶ËÞTšz͑W®,£ùž¥Ö˜›‹%|$f‘F”ØßÌßznÅO§Cƒ¬!š¥ÿ£TehXãpýÁ©/yþô@=rÚ 0000015924 00000 n %���� P273 - Avoid release to the environment. Although employees may use ammonium hydroxide both at home and at work, employers must ensure they are aware of the unique dangers of the chemical. Ammonia vapors are released when heated. One Reagent Lane. 0000002525 00000 n AMMONIA SOLUTION, STRONG, AMMONIA WATER, AMMONIA, AQUEOUS SOLUTION, AMMONIUM HYDROXIDE, AMMONIUM HYDROXIDE ((NH4)(OH)), AQUA AMMONIUM, HARTSHORN SPIRIT, SPIRIT OF HARTSHORN, and STRONG AMMONIA SOLUTION When dissolved in water, Ammonia forms Ammonium Hydroxide (H5NO). 0000011267 00000 n >> Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. Material uses: Laboratory Reagent. *Please select more than one item to compare ý„da BL:†nCò“é [Ö ×-|ëúÀ7LôÿDÄÛÚVíp)J0æ[email protected]û‘ãä˜ñVÖêg,0G'¹ ¬bÎm™Ë–õ•@ÅëæåºS› ª‚ÕÛò‹å0†(ĀxÁX,C­Ý ü¥F$°üšÿÛ On burning: release of toxic and corrosive gases/vapours (nitrous vapours). Revised on 04/21/2016 Page 1 of 6 Safety Data Sheet Ammonium Hydroxide 3N 1. 0000007425 00000 n It is soluble in water. /Producer(Sub Systems, Inc.)/CreationDate(D:20190425105311+04'00')/ModDate(D:20190425105311+04'00')/Creator(Sub Systems, Inc.) 7732-18-5), 98-99% Section 4: First Aid Measures 0000012304 00000 n 0000001926 00000 n Evolves toxic gaseous ammonia with strong bases. Conditions to Avoid Avoid ammonium hydroxide contact with chlorine, which forms a chloramine gas, which is a primary skin irritant and sensitizer. Linear Formula NH 4 OH . Safety Data Sheet Ammonium Hydroxide Issue Date: 12/30/2015 V1.0 1. Print Share on: Evidence. It is corrosive to metals and tissue. Health Hazard Ammonium hydroxide solutions are alkaline solutions, meaning they have high pH level. startxref The gas is an eye, skin and respiratory irritant. 0000006041 00000 n Ventilation rates should be matched to conditions. Causes severe skin burns and eye damage. "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k���K�^��^'��d4k����˗;�g����_�u_�������L��OC6���($uiz["��Dڻw�#�޽���6����"������UH��8/�?CZ7�����D|z�?���W5M��78����k"^�8�ö����$���p(�?kӴ������ׅL�}��~�Gm�ֽ�{{���>~�O4��v���{���x��?�O�g�|���4k�j�uG�|����ig�I���f�i����7�������x����z�ίgu���}�=�h������FR��G�\:��X���ÔY�S�so/����m��{��^��n�g��������J�?�_����˝��l��R�� ~ ������!J�����s��A���'Y*��ߤ\=���f/�� ��3[��= ����'u~ͻ�/���g�����i���� �_C�|�2��S�A^�����|z��;���^���jy�h>~�� ��{�7? 0000003112 00000 n It is also a highly corrosive chemical and a skin, eye, and respiratory irritant. Such a precipitate can explode on stirring [MCA Case History 1554 1968]. Level of Concern . Beilstein/REAXYS Number 3587154 . Company. The vapors are extremely irritating to the eyes. <<0E3A66ABCCE85E48B6E7192D2C7FA130>]>> 0000006157 00000 n Exposure Routes. ... in this product - not the product itself - compared to other product formulations. 0000019076 00000 n Ammonia and Ammonium Hydroxide are used in a large variety of products including hair dyes, hair bleaching products, shaving cream and hair grooming products. 0000010276 00000 n Take all appropriate precautions. inhalation, ingestion (solution), skin and/or eye contact (solution/liquid) Symptoms. 4 0 obj MDL number MFCD00066650 However, ammonium hydroxide is one exception. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls 0000004534 00000 n 0000001439 00000 n For use on containers that store Ammonium Hydroxide to ensure the workplace is aware of the immediate chemical hazards that are present. Reacts with aqueous silver nitrate sodium hydroxide to give a black precipitate of silver nitride. Ammonia can be mixed with water and sold as ammonium hydroxide, or used in compressed gas as anhydrous ammonia (meaning without water). As a result, ammonium hydroxide is a severe eye, skin, and respiratory tract irritant, and readily burns tissue with which it comes in contact. : with (some) halogens compounds, with … 0000002366 00000 n Toxic by all routes (ie, inhalation, ingestion, and dermal contact), exposure to this colorless, intensely pungent-smelling liquid may occur from its use in fertilizers, dyes, explosives, plastics, cleansing agents, fibers, and resins. Search results for 1336-21-6 at Sigma-Aldrich. '’ü¸Š¥q Reacts extremely violently with dimethyl sulfate [NFPA 491M 1991]. Product Name: Ammonium Hydroxide (10% to 30%) Synonyms: Ammonium Hydroxide Solutions, Aqua Ammonia, Aqua Ammonia Solutions, Ammonia Solutions, Ammonia Aqueous, Ammonia Water CAS REGISTRY NO: 1336-21-6 Supplier: Tanner Industries, Inc. 735 Davisville Road, Third Floor Southampton, PA 18966 Website: www.tannerind.com Telephone (General): 215-322-1238 May adversely affect pH of aquatic ecosystems. Strong oxidizers, acids, halogens, salts of silver & zinc [Note: Corrosive to copper & galvanized surfaces.] Direct contact with the eyes can cause blindness if not washed away immediately within the first 10 seconds. 1 0 obj PRODUCT AND COMPANY IDENTIFICATION Product Name: Ammonium Hydroxide 3N Synonyms/Generic Names: Aqueous Ammonia; Strong Ammonia Solution; Stronger Ammonia Water Product Number: 8133 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. endstream endobj 29 0 obj <. Incompatibilities & Reactivities. xref 0000009368 00000 n 3 Effective date : 11.05.2014 Page 2 of 6 Ammonium Hydroxide, 3M Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com 0000001303 00000 n AMMONIUM HYDROXIDE reacts exothermically with acids. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9402 Signal Word DANGER SECTION 2 — HAZARDS IDENTIFICATION Hazard class: Acute toxicity, oral (Category 4). 0000018685 00000 n Ammonium hydroxide is highly toxic whether it is inhaled, ingested, or absorbed through the skin. %PDF-1.4 HAZARDS IDENTIFICATION Terra Industries Inc. Terra Centre – 600 Fourth Street Sioux City, Iowa … 0000006391 00000 n %PDF-1.6 %âãÏÓ 2.4. Y>ákî'ÅI9‰bÀrR/OÕIÚϒ‡à÷+aoÁ¶’ßï? SAFETY DATA SHEET: AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS A631.7A INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800 … Section 3: Composition / Information on Ingredients Ammonium Hydroxide, (1336-21-6), 1-2% as Ammonia Water: (CAS No. Ammonia gas is generally not considered a serious fire or explosion hazard because ammonia/air mixtures are difficult 0000008433 00000 n 0000003840 00000 n << It can be denoted by the symbols NH 3 (aq). 0 Workers in all industries should know that, despite its common usage, ammonia poses health risks and hazards that require proper use of personal protective equipment (PPE) and safe use and handling procedures. fInhaling Ammonium Hydroxidecan irritate the lungs causing coughing and/or shortness of breath. Ammonium Hydroxide / 1336-21-6 39.1% 25 ppm TWA Water / 7732-18-5 60.9% 35 ppm STEL 50 ppm PEL Contains 19% ammonia as NH3 300 ppm IDLH 3. Fisher Scientific. 28 34 Serious Eye Damage/Eye Irritation Category 1. Possibility of Hazardous Reactions Ammonium hydroxide will react exothermically with acids. PRODUCT AND COMPANY IDENTIFICATION Product name: Ammonium Hydroxide ~30% Product code: 05870-16 Supplier: StatLab Medical Products 2090 Commerce Drive McKinney, TX 75069 800-442-3573 972-436-1369 Fax statlab.com Synonym: None. 0000018893 00000 n X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe][email protected]�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? Ammonium hydroxide, ACS reagent, 28-30% solution in water, ACROS Organics™ CAS=1336-21 … Very toxic to aquatic life . Ammonia vapor, in concentrations of 16-25% volume by weight in air, is flammable, toxic by inhalation and corrosive. Wear appropriate protective clothing to … For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam extinguishers. 0000004305 00000 n Ammonium hydroxide is not a flammable liquid; however, ammonia gas is flammable. 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Product formulations hazard Communication Standard ( 29 CFR 1910.1200 ) Issue Date: 12/30/2015 V1.0 1 No! The hydrated form or a colorless liquid with a strong ammonia -like odor [ NFPA 491M 1991 ] copper galvanized. Inhaled, ingested, or absorbed through the skin solution/liquid ) Symptoms will exothermically... Whether it is inhaled, ingested, or absorbed through the skin release! Is also a highly corrosive chemical and a skin, eye, skin and respiratory.! Considered a serious fire or explosion hazard because ammonia/air mixtures are difficult Incompatibilities & Reactivities explosion. Hydroxide Issue Date: 12/30/2015 V1.0 1 - compared to other product formulations heating: release toxic. ( some ) halogens compounds, with … Ammonium hydroxide will react exothermically with acids aq ) NFPA 1991... Be denoted by the symbols NH 3 ( aq ) safety Data Sheet according to and... 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Everything from household cleaners to industrial processes, it is also a highly corrosive chemical and a skin,,., with … Ammonium hydroxide is very volatile and may release ammonia as ammonium hydroxide hazards!

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